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  • 1.  Vitrine repair

    Posted 12-01-2022 15:36
    I am interested in attempting to repair vitrines that would exhibit natural history specimens. Does anyone have any recommendations for working with acrylic sheeting, adhesives, and museum specimens? I would prefer to work with materials and methods that are conservation approved, I just don't know where to look to find them! I poked around in the Materials Testing Results on the Wiki page for adhesives, but am still lost.

    The original vitrine joins have partially separated, and some of the resulting gaps have a flat ribbon-like adhesive that zig zags between the sheeting. I do not have access to the original build specifications, and am unsure as to how to figure out what was originally used. I know I do not want to cross-link any material, and I definitely do not want to cause damage to any specimen that might be displayed in the future. Will I need to test the "ribbon" adhesive? If so, how? Any help or direction would be greatly appreciated.

    Thank you all,
    Heidi Mead

    ------------------------------
    Heidi Mead (she, her)
    Vertebrate Fossil Preparator
    William P. Wall Museum of Natural History
    Georgia College
    Milledgeville GA 31061
    ------------------------------


  • 2.  RE: Vitrine repair

    Posted 12-01-2022 16:23
    Hi Heidi,
    As the acting C2C Care community monitor, I'd like to thank you for returning to the community and will be passing your previous and current inquiries to our C2C Care experts who specialize in exhibit preparation and mount making. In the meantime, if anyone else has advice or recommendations, please pass them along!

    ------------------------------
    Sharon Fickeissen
    Connecting to Collections Care Monitor
    Senior Library Conservation Technician
    Hagley Museum & Library
    Wilmington DE
    sfickeissen@hagley.org
    ------------------------------



  • 3.  RE: Vitrine repair

    Posted 12-02-2022 09:55
    It sounds like they used a double sided adhesive tape to seal the acrylic?  If that's the case, there are a couple of acrylic double sided adhesives in the Materials Testing Wiki database that should work and produce better than average test results. Without seeing the vitrines, it's difficult to say what the actual situation is, but it's more common for acrylic sheet to be joined by introducing a solvent or a solvent based glue to the join that to use a tape.  This site has a good general description: https://www.acmeplastics.com/content/a-guide-to-gluing-acrylic-plastic-to-plastic/
    If you use solvent based glues, you'll find that the vast majority of the formulation is solvent that's meant to soften the acrylic to allow fusing of the two pieces. Solvent based acrylic glues don't contain a lot of solids or materials that are left behind in the joint, though there are some, making testing the glues difficult.  That said, they've been used for decades in the field without issue, as far as I am aware.

    ------------------------------
    Eric Breitung
    Research Scientist
    Metropolitan Museum of Art, Department of Scientific Research
    New York NY
    (217) 331-8469
    ------------------------------



  • 4.  RE: Vitrine repair

    Posted 12-05-2022 16:44
    Good morning,

    I have attached images of the adhesive ribbon "zig-zag" I am seeing between the edges of the acrylic sheeting. Perhaps I should have said weaving instead...
    I have since removed a long narrow stretchy and slightly sticky ribbon of the adhesive. It did not want to come off easily, just continued to stretch out, then broke, and shrank up slightly. There are tacky remnants remaining on the edges of the acrylic where I pulled my sample from (and scraped with a scalpel). The sample is tacky to my fingers, forceps, scalpel and glass shell vial. It has yet to dissolve in acetone, 95% ethyl alcohol, or diH2O. Next up will be testing with a flame. Thank you so much for all the suggestions!

    ------------------------------
    Heidi Mead (she, her)
    Vertebrate Fossil Preparator
    William P. Wall Museum of Natural History
    Georgia College
    Milledgeville GA 31061
    ------------------------------



  • 5.  RE: Vitrine repair

    Posted 12-05-2022 16:44
    Flaming follow-up, whatever this adhesive is, it likes to burn. Holding the end of a 1" adhesive strand horizontal with forceps, and lighting the opposite tip with a standard lighter, the strand immediately begins to burn, sizzle and sparkle, leaving a crispy blackened end in the forceps. Repeated thrice.

    It will be extremely difficult to remove the adhesive from the acrylic without causing additional damage. There is enough tack to this stuff that it will stick back together if folded upon itself. I had high hopes for finding a solution.

    ------------------------------
    Heidi Mead (she, her)
    Vertebrate Fossil Preparator
    William P. Wall Museum of Natural History
    Georgia College
    Milledgeville GA 31061
    ------------------------------



  • 6.  RE: Vitrine repair

    Posted 12-02-2022 18:55

    @Heidi Mead
    Below is the response from Jamie Hascall, Craftsman, Trainer, Consultant at MountMaking Focus
    Hi Sharon and Heidi,

    I've been looking at this question and trying to come up with a reasonable path forward for you. As I figured, it's going to take a little bit of explanation so please bear with me.

    I feel that gluing acrylic is a bit of a black art. I have had very uneven results any time I've tried it and have never tried to fabricate vitrines as getting a clear glue line on a long running joint requires tooling and expertise that I do not have. It is one of the reasons vitrines are so expensive, and thus why your predicament is so urgent.

    I'll start with the basics of gluing acrylic. The "glues" that are used to join acrylic are solvents that are actually softening the acrylic plastic to the point where the two sides weld together. (Generally Methylene Chloride or other very nasty solvents. They must be used with good ventilation and PPE.) In the process, the plastic swells, and then shrinks again. As joints age, that shrinking seems to continue and at some point they weaken and becomes much more prone to failure. Close inspection will show that the area of clean line of the joint will start to show little uneven edges or even voids within the joint. Failure is likely to start at the ends of the joints as it is the least supported point and will slowly progress from there. If a joint fails quickly on a new vitrine, it is likely a manufacturing defect such poor joint fit or insufficient annealing, a slow heating and cooling done after glue-up done to relieve stresses within the assembled box.

    Your thoughts of temperature change as a cause of failure is reasonable, but I imagine that more likely culprit is the repeated flexing of the entire vitrine that occurs with the physical rubbing of cleaning. Given that there needs to be enough room between the accompanying stand or backboard to get the vitrine on and off and not have the shrink and swell cycle of each component cause damage, there is enough play that everything will inevitably flex and move a little. As with so many things, it is the cumulative effect of little actions that cause the most change. The acrylic sheet is an intrinsically flexible material and each time it is cleaned, some amount of force will travel to the edge where there is a very narrow and inflexible joint that is maybe 6mm wide. The leverage will be a significant multiplier of the force and with that in mind, it's a wonder that vitrines last as long as they do, and is a testament to the strength of a good glue joint. 

    So now, the question is how to proceed with a repair. One of the issues is that the solvent glues that are used are generally water-thin and require a very square and close fitting joint to provide the conditions for proper capillary action to draw the glue into the joint. This is why the fabrication of vitrines is so difficult. The damaged joint no longer has the clean surfaces and tight fit that will easily draw the glue into the joint and allow it to re-soften and weld. Thus, you'll need to use one of the slightly thickened versions of the cement to help fill gaps. (The cement is the solvent plus a little acrylic dust as a bulking filler.) I would recommend IPS Weld-On 16 as the best choice. (Super glue/cyanoacrylate glues will not work well with clear acrylic.) The hard part is that you've got a fairly close fitting joint that is still good and tight at the tip of the break so working in glue is not easy. 

    I would plan on having the vitrine on a bench for stability and ability to clamp it for a period of time. This repair will not be able to be done in-situ. I'd tape the corner just above the tip of the failure to keep that part of the joint supported. Opening up the broken joint from the bottom with a small probe should allow you to place a line of glue into the void and then let it come back together and clamp it until the glue has set. Any glue that is trapped under tape or a clamping caul will bond and mar the surface so you'll need to find ways of clamping that can stabilize the parts but not trap glue. If you possibly have a vitrine that is badly enough damaged that you will not be using it, you can use it as a test bed for your technique as it's going to take some learning to make this work well. Letting the whole thing set overnight will be important to let it gain strength needed.

    I'm including some links to a list of the glues used and a Fabrication Resources page from Plaskolite plastics, one of the large manufacturers of acrylic. Their Optix Fabrication Manual is really good.

    I hope that helps. Please post any follow up questions or get in touch with me directly if I can be of further help.

    Good luck,

    Jamie

    Jamie Hascall
    Craftsman, Trainer, Consultant
    Mountmakingfocus.com
    jamie@mountmakingfocus.com
    Seattle, WA

    206-954-4141

    On Dec 2, 2022, at 8:11 AM, Sharon Fickeissen <sfickeissen@Hagley.org> wrote:

    Hello Jamie & Rachael, 

    As the acting C2C Care community monitor, I am passing Heidi's related inquiries on to you, the C2C Care experts specializing in exhibit preparation and mount making. Heidi Mead, Vertebrate Fossil Preparator at the William P. Wall Museum of Natural History in Georgia posted this initial query:

    I am wondering if any of you might have some insight into why our expensive vitrines might have suddenly popped open at the seams.

    Our housekeeping methods for cleaning cases only involves a very lightly dampened cloth (distilled water). There is no crazing.

    We do not move these pedestals, and they have been in place for close to ten years.

    12 out of our 21 vitrines are exhibiting gaping at the sides, top, base, or all seams. There does not appear to be any one pattern. All cases are in the same room, some along walls, some centrally located.

    The vitrines were purchased in lots from the same vendor, however the manufacturer may have differed. I cannot tell from our invoices.

    We do use a data logger, however, due to an oversight, the logger has not been recording.

    I am inclined to think this is due to some kind of environmental factor, like sudden temperature fluctuations. We had some sudden drops in the outside temperature.  Without the data logger though....

     

    I have spoken with the vendor from whom we purchased, and they are inquiring about how we might repair these. They did acknowledge that they no longer use the same manufacturer. This will be a huge task, and I would truly appreciate any thoughts any of you might have.

     

    This is her more recent follow-up:

    I am interested in attempting to repair vitrines that would exhibit natural history specimens. Does anyone have any recommendations for working with acrylic sheeting, adhesives, and museum specimens? I would prefer to work with materials and methods that are conservation approved, I just don't know where to look to find them! I poked around in the Materials Testing Results on the Wiki page for adhesives, but am still lost.

    The original vitrine joins have partially separated, and some of the resulting gaps have a flat ribbon-like adhesive that zig zags between the sheeting. I do not have access to the original build specifications, and am unsure as to how to figure out what was originally used. I know I do not want to cross-link any material, and I definitely do not want to cause damage to any specimen that might be displayed in the future. Will I need to test the "ribbon" adhesive? If so, how? Any help or direction would be greatly appreciated.

    Link to post: https://community.culturalheritage.org/discussion/vitrine-repair-1?ReturnUrl=%2fcommunities%2fcommunity-home%2fdigestviewer%3fcommunitykey%3defc8a209-1e74-4c1b-80d7-cb26db836184

     

    You are welcome to respond through me, directly to her (heidi.mead@gcsu.edu), or in the community (https://community.culturalheritage.org/home). Any information you can provide would be greatly appreciated.

     

    Sharon Fickeissen

    Connecting to Collections Care Monitor

    Senior Conservation Technician

    Hagley Museum & Library

    sfickeissen@hagley.org



    ------------------------------
    Sharon Fickeissen
    Connecting to Collections Care Monitor
    Senior Library Conservation Technician
    Hagley Museum & Library
    Wilmington DE
    sfickeissen@hagley.org
    ------------------------------



  • 7.  RE: Vitrine repair

    Posted 12-02-2022 18:55

    An updated response from Jamie:

    Hi Heidi,

    I hadn't quite understood your statement about the "ribbon" of adhesive but just took another look at your post and think I get it. It sounds like your vitrine was built with a silicone glue instead of a solvent weld as I described in my previous post. The unfortunate thing is that silicone does not adhere well to acrylic, and once a silicone is used in such a situation, the join is probably contaminated in such a way as to make it unable to be repaired in the fashion I described. I would try to grab a bit of the ribbon with a set of tweezers and try to pull out a sample. I'm not sure a procedure for determining if it is silicone, but if it's stretchy and clear, it's likely to be either a silicone or a urethane, and probably the former. If that is the case, I really don't know how to advise you to repair your vitrine as I'd be surprised if solvent cement will function properly. The only way to find out is to make one vitrine sacrificial and try out solutions on it. Sorry I don't have better news.

     

    On the subject of materials testing, I think the normal glues used on acrylic are considered safe. Unless you have an extremely sensitive material being displayed (silver, copper, lead, or possibly some mineral specimens) you're probably likely to be fine as the surface are of the edge of a glue joint is extremely small and most glues we use for such work tend to cure very completely with sufficient time to off-gas. If I'm really concerned about something on display I sometimes recommend including a scavenger such as activated charcoal in he display environment.

     

    Good luck,

    Jamie

     

    Jamie Hascall
    Craftsman, Trainer, Consultant
    Mountmakingfocus.com
    jamie@mountmakingfocus.com
    Seattle, WA

    206-954-4141



    ------------------------------
    Sharon Fickeissen
    Connecting to Collections Care Monitor
    Senior Library Conservation Technician
    Hagley Museum & Library
    Wilmington DE
    sfickeissen@hagley.org
    ------------------------------